Combination of Cp*RhIII -Catalyzed C-H Activation and a Wagner-Meerwein-Type Rearrangement.
Combination of Cp*RhIII -Catalyzed C-H Activation and a Wagner-Meerwein-Type Rearrangement.
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DOI：
10.1002/anie.201610117
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发表时间：
2017-01
影响因子：
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通讯作者：
Xiaoming Wang;Andreas Lerchen;T. Gensch;T. Knecht;C. Daniliuc;F. Glorius
中科院分区：
文献类型：
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作者：
Xiaoming Wang;Andreas Lerchen;T. Gensch;T. Knecht;C. Daniliuc;F. Glorius
首次成功地实现了CP*RhIII催化的C-H活化和Wagner-Meerwein重排的结合。因此，在温和的条件下，N-苯氧乙酰胺和7-氮杂苯冰片二烯的偶联反应(低至0.5mol%的Rh催化剂)，很容易获得桥联的多环分子。
A combination of Cp*RhIII -catalyzed C-H activation and Wagner-Meerwein-type rearrangement was successfully achieved for the first time. Thus, bridged polycyclic molecules that are not readily accessible by other means were accessed under mild conditions with high efficiency (as low as 0.5 mol % Rh catalyst) in the coupling of N-phenoxyacetamide with 7-azabenzonorbornadiene.