Reversible Electron Transfer in a Linear {Fe2Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion
Reversible Electron Transfer in a Linear {Fe2Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion
复制标题
热处理和光辐照诱导线性 {Fe2Co} 三核配合物中的可逆电子转移
DOI：
10.1002/anie.201201305
复制
发表时间：
2012-01-01
影响因子：
16.6
通讯作者：
Duan, Chun-Ying
中科院分区：
文献类型：
--
作者：
Liu, Tao;Dong, Da-Peng;Duan, Chun-Ying
光变化：一个线性氰基桥接的fe2co化合物（见图）在三核簇中表现出可逆的、热诱导的合作电荷转移转变，伴随着自旋转变和极性-非极性转变。光照射也能引起磁性和极性的变化。
A light change: A linear cyanido-bridged Fe 2 Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar-nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light.