Upconversion luminescence, temperature sensing and internal heating behaviors of Er3+/Yb3+/Fe3+-tridoped NaBiF4 nanoparticles
Upconversion luminescence, temperature sensing and internal heating behaviors of Er3+/Yb3+/Fe3+-tridoped NaBiF4 nanoparticles
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DOI：
10.1016/j.jallcom.2019.07.054
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发表时间：
2019-10-15
影响因子：
6.2
通讯作者：
Li, Weiping
中科院分区：
文献类型：
--
作者：
Du, Peng;Zhang, Quan;Li, Weiping
ER3+/YB3+/Fe-3+tridop的NABIF4纳米颗粒通过室温下的简单沉淀反应方法合成。详细研究了Fe3+离子对开发样品的微结构和上转换（UC）发光特性的影响。通过FE3+离子掺杂工程，观察到绿色和红色UC发射强度的增强，Fe3+离子的最佳掺杂浓度揭示为30 mol％。由于荧光强度比技术，研究了在303-543 K的温度范围内所得产物的光学热性能，并且所研究纳米颗粒的最大传感器敏感性为0.0053 k-1，在543 K时。研究了所获得的纳米颗粒的行为，并在将泵功率设置为260 mW时，将产物温度提高到399 K。我们的系统和互补研究表明，具有出色的UC行为的ER3+/YB3+/Fe3+Tri-Tri-doped Nabif4纳米颗粒被固定为纳米热计和光学加热器的下一代有前途的候选者。 （c）2019年由Elsevier B.V.出版
Series of Er3+/Yb3+/Fe-3+-tridoped NaBiF4 nanoparticles were synthesized through a simple precipitation reaction method at room temperature. The effect of the Fe3+ ions on the microstructure and upconversion (UC) luminescence properties of the developed samples were studied in detail. Through the Fe3+ ions doping engineering, the enhancement in both green and red UC emission intensities were observed and the optimal doping concentration for Fe3+ ions was revealed to be 30 mol%. Owing to the fluorescence intensity ratio technology, the optical thermometric performances of the resultant products in the temperature range of 303-543 K were investigated and the maximum sensor sensitivity of the studied nanoparticles was 0.0053 K-1 at 543 K. Moreover, the internal heating behaviors of the obtained nanoparticles were investigated and the product temperature was improved to 399 K when the pump power was set at 260 mW. Our systematic and complementary studies suggested that the Er3+/Yb3+/Fe3+-tri-doped NaBiF4 nanoparticles with splendid UC behaviors were poised as next-generation promising candidates for nanothermometer and optical heaters. (C) 2019 Published by Elsevier B.V.