Novel Extended Linear Structure of Decavanadate Anions Linked by Bis(4-Pyridinium) Disulfide (H2dpds), {(H2dpds)2[V10O26(OH)2]·10H2O}n
Novel Extended Linear Structure of Decavanadate Anions Linked by Bis(4-Pyridinium) Disulfide (H2dpds), {(H2dpds)2[V10O26(OH)2]·10H2O}n
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双(4-吡啶)二硫化物(H2dpds)连接的十钒酸盐阴离子的新型扩展线性结构，{(H2dpds)2[V10O26(OH)2]·10H2O}n
DOI：
10.1246/cl.1999.291
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发表时间：
1999
影响因子：
1.6
通讯作者：
H. Matsuzaka
中科院分区：
文献类型：
--
作者：
M. Kondo;K. Fujimoto;T. Okubo;A. Asami;S. Noro;S. Kitagawa;T. Ishii;H. Matsuzaka
合成了新型多孔配位聚合物{(H2dpds)2[V10O26(OH)2]·10H2O}n（H2dpds = 双(4-吡啶鎓)二硫化物）并进行了结构表征。 X 射线分析表明十钒酸根阴离子通过 H2dpds 配体双桥联以提供一维结构。该网络提供沿 c 轴尺寸约为 2 × 4 A 的通道腔。
New porous coordination polymer, {(H2dpds)2[V10O26(OH)2]·10H2O}n (H2dpds = bis(4-pyridinium) disulfide), was synthesized and structurally characterized. X-ray analysis demonstrates that the decavanadate anions are doubly bridged by H2dpds ligands to provide a one-dimensional structure. This network affords channeling cavities with dimension of about 2 × 4 A along the c-axis.