Formation of potentially prebiotic amphiphiles by reaction of beta-hydroxy-n-alkylamines with cyclotriphosphate.
Formation of potentially prebiotic amphiphiles by reaction of beta-hydroxy-n-alkylamines with cyclotriphosphate.
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DOI：
10.1002/anie.200700394
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发表时间：
2007-05
影响因子：
--
通讯作者：
Lee B Mullen;J. Sutherland
中科院分区：
文献类型：
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作者：
Lee B Mullen;J. Sutherland
(给出的化学方程式)长处和短处：在水中，长链β-羟基-正烷基胺与环三磷酸反应生成O-单磷酸盐。与短链对羟基正烷基胺一起，生成N-三磷酸盐。这种差异是由于长链化合物形成表面活性组装体所致。这种表面活性剂对反应性的控制可能与两亲分子的生前形成有关。P：磷酸盐单元。2007 Wiley-VCH Verlag GmbH&Co.KGaA。
(Chemical Equation Presented) The long and the short of it: In water, long-chain β-hydroxy-n-alkylamines are converted to their O-monophosphates by reaction with cyclotriphosphate. With short-chain pVhydroxy-n-alkylamines, N-triphosphates are formed instead. The difference results from the formation of surfactant assemblies from the long-chain compounds. This surfactant control of reactivity may be of relevance to the prebiotic formation of amphiphiles. P: phosphate unit.© 2007 Wiley-VCH Verlag GmbH & Co. KGaA.