Convenient and efficient reduction of 1,1′-binaphthyls to H8-1,1′-binaphthyl derivatives with Pd and Ru catalysts on solid support
Convenient and efficient reduction of 1,1′-binaphthyls to H8-1,1′-binaphthyl derivatives with Pd and Ru catalysts on solid support
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DOI：
10.1021/jo0497609
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发表时间：
2004-04-30
影响因子：
3.6
通讯作者：
Börner, A
中科院分区：
文献类型：
--
作者：
Korostylev, A;Tararov, VI;Börner, A
研究了Pd和Ru固载金属催化剂催化手性2，2 ′-功能化1，1 ′-联萘加氢合成5，5 ′，6，6 ′，7，7 ′，8，8 ′-八氢-1，1 ′-联萘衍生物的方法。在大多数情况下，在反应过程中没有观察到外消旋化。
Hydrogenation of chiral 2,2'-functionalized 1,1'-binaphthyls with Pd and Ru solid-supported metal catalysts was found to be a clean and convenient pathway to 5,5',6,6',7,7',8,8'-octahydro-1,1'-dinaphthyl derivatives. In most cases no racemization was observed in the course of the reaction.