Electron transfer-induced reduction of organic halides with amines
Electron transfer-induced reduction of organic halides with amines
复制标题
DOI：
10.1039/c8cc02445f
复制
发表时间：
2018-06-04
影响因子：
4.9
通讯作者：
Wu, Yen-Ku
中科院分区：
文献类型：
--
作者：
Fukuyama, Takahide;Fujita, Yuki;Wu, Yen-Ku
通过使用胺作为牺牲氢源来研究各种有机卤化物的还原。用三乙胺进行紫外光诱导的乙烯基卤化物和芳基卤化物的还原反应顺利进行，得到相应的还原产物。高温加热也会引起还原反应，DABCO（1,4-二氮杂双环[2.2.2]辛烷）也是一种良好的还原剂。
Reduction of a variety of organo halides was examined by using amines as a sacrificial hydrogen source. UV light-induced reduction of vinyl and aryl halides with triethylamine proceeded smoothly to give the corresponding reduced products. High temperature heating also caused the reduction and DABCO (1,4-diazabicyclo[2.2.2]octane) also served as a good reducing reagent.