Comptes Rendus de l'Académie des Sciences.
Comptes Rendus de l'Académie des Sciences.
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Comptes Rendus de lAcadémie des Sciences。
DOI：
10.1021/ja02149a001
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发表时间：
1879
影响因子：
15
通讯作者：
A. Bourgougnon
中科院分区：
文献类型：
--
作者：
A. Bourgougnon
在300摄氏度，氰与锌、镉、铁在封闭的管道中化合而不产生氮。与锌的反应在常温下发生，在接触几天后，但仅在金属表面上;在100 ℃。反应在三至四小时后进行。铜和铅在100 ℃或300 ℃时不发生任何反应，但在500 ℃时生成少量氰化物，并产生含碳物质和氮。银与汞在低温和高温下均不发生反应。Cahours和Demar 9ay。丁基锡是在密闭烧瓶中加热25天，使碘化异丁基与锡反应而生成的。将碘化戊基与锡在密闭烧瓶中加热25天，即可得到Stanamyl。
At 300 C., cyanogen combines with zinc, cadmium, iron, in a closed tube, without production of nitrogen. The reaction with zinc takes place at ordinary temperature, after a contact of some days, but only on the surface of the metal; at 100 C. the reaction takes place after three to four hours. Copper and lead did not give any reaction at 100 or 300, but at 500 a small quantity of cyanides was formed, with production of a carbonaceous substance and of nitrogen. Silver and mercury did not give any reaction at low or high tem-peratures.Organometallic Radicles of Tin, A. Cahours and Demar9ay.—Stanbutyl is produced by the action of iodide of iso butyl upon tin, in a closed flask heated for twenty-five days. Stanamyl is obtained by heating iodide of amyl with tin for twenty-five days, in a closed flask.