Polymer deformation in terms of spherulites

Polymer deformation in terms of spherulites
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DOI:
10.1007/bf01500379
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发表时间:
1965-08
期刊:
Kolloid-Zeitschrift und Zeitschrift für Polymere
影响因子:
--
通讯作者:
I. L. Hay;A. Keller
I. L. Hay;A. Keller
中科院分区:
其他
文献类型:
--
作者:
I. L. Hay;A. Keller

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ESR研究和耗氧量测量表明,辐照石蜡的氧化遵循自由基链式反应,导致羟基的形成。通过红外光谱和分子量研究对羟基的降解产物进行了追踪。通过定量分析,建立了测定辐照石蜡氧化降解的反应方程。
ESR investigations and measurements of oxygen consumption show, that the oxidation of irradiated paraffin follows a radical chain reaction which leads to the formation of hydroperoxy groups. The degradation products of the hydroperoxy groups are traced by IR and molecular weight studies. The quantitative analysis results in the formulation of reaction equations which determine the oxidative degradation of the irradiated paraffin.