Preparing (Multi)Fluoroarenes as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C-F Bond Cleavage.
Preparing (Multi)Fluoroarenes as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C-F Bond Cleavage.
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DOI：
10.1021/jacs.6b02337
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发表时间：
2016-04
影响因子：
15
通讯作者：
Jing-Feng Zhou;Maximilian W. Kuntze‐Fechner;R. Bertermann;Ursula S. D. Paul;Johannes H. J. Berthel;A. Friedri
中科院分区：
文献类型：
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作者：
Jing-Feng Zhou;Maximilian W. Kuntze‐Fechner;R. Bertermann;Ursula S. D. Paul;Johannes H. J. Berthel;A. Friedri
报道了[Ni(ime)2]催化氟芳烃通过C-F键活化和双（pinacolato）二硼（B2pin2）转金属转化为芳基硼酸pinacol酯。不同氟化程度的部分氟化芳烃转化为相应的硼酸酯。
The [Ni(IMes)2]-catalyzed transformation of fluoroarenes into arylboronic acid pinacol esters via C-F bond activation and transmetalation with bis(pinacolato)diboron (B2pin2) is reported. Various partially fluorinated arenes with different degrees of fluorination were converted into their corresponding boronate esters.