Preparation of Open-Cage Fullerenes and Incorporation of Small Molecules Through Their Orifices
Preparation of Open-Cage Fullerenes and Incorporation of Small Molecules Through Their Orifices
复制标题
开笼富勒烯的制备以及通过其孔口掺入小分子
DOI：
10.1002/adma.200903705
复制
发表时间：
2010-04-06
影响因子：
29.4
通讯作者：
Huang, Huan
中科院分区：
文献类型：
--
作者：
Gan, Liangbing;Yang, Dazhi;Huang, Huan
开笼富勒烯可以作为水、氮或氢等小分子的宿主，形成面内富勒烯。在简要总结了碳、氮和氧在富勒烯骨架中插入以形成高富勒烯之后，综述了在富勒烯表面形成孔的方法。描述了扩孔和通过孔口插入原子或分子以形成面内富勒烯的技术。最后，考虑了随后关闭孔洞的可能性。
Open-cage fullerenes can act as hosts for small molecules such as water, nitrogen, or hydrogen, forming endohedral fullerenes. Following a brief summary of carbon, nitrogen, and oxygen insertion in the fullerene framework to form homofullerenes, methods of creating a hole in the fullerene surface are surveyed. Techniques of hole enlargement and the insertion of atoms or molecules through the orifice to form endohedral fullerenes are described. Finally, the possibility of subsequent closure of the hole is considered.