Polymerisation of ethene by the novel titanium complex [Ti(Me3SiNCH2CH2NSiMe3)Cl2]; a metallocene analogue

Polymerisation of ethene by the novel titanium complex [Ti(Me3SiNCH2CH2NSiMe3)Cl2]; a metallocene analogue
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新型钛络合物[Ti(Me3SiNCH2CH2NSiMe3)Cl2]聚合乙烯;

DOI:
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发表时间:
1996
期刊:
影响因子:
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通讯作者:
A. Mccamley
A. Mccamley
中科院分区:
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文献类型:
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作者:
S. Tinkler;R. Deeth;D. Duncalf;A. Mccamley

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三甲基硅烷化二胺配体 (Me3Si)NHCH2CH2NH(SiMe3) 与钛 (IV) 前体反应得到新型扭曲四面体配合物 [Ti(Me3SiNCH2CH2NSiMe3)Cl2],当被甲基铝氧烷活化时,它是一种活性乙烯聚合催化剂。
Reaction of the trimethylsilylated diamine ligand (Me3Si)NHCH2CH2NH(SiMe3) with titanium(IV) precursors affords the novel distorted-tetrahedral complex [Ti(Me3SiNCH2CH2NSiMe3)Cl2] which, when activated by methylaluminoxane, is an active ethene polymerisation catalyst.