Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods
Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods
复制标题
异质结构金属硫化物纳米棒阳离子交换过程中的正交反应性和界面驱动选择性
DOI：
10.1039/d1cc07190d
复制
发表时间：
2022
影响因子：
4.9
通讯作者：
Schaak, Raymond E.
中科院分区：
文献类型：
--
作者：
Fagan, Abigail M.;Steimle, Benjamin C.;Schaak, Raymond E.
我们报告的预测准则的亚化学计量的阳离子交换模型的双组分金属硫化物纳米棒含有类似硬度的二价阳离子。晶胞体积的变化，阳离子半径，溶解度常数，和固态界面的影响选择性在亚化学计量交换的Cu+时，多种产品是可能的。
We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu+ when multiple products are possible.