Reversible dinitrogen binding to [Cp'Fe(NHC)] associated with an N2-induced spin state change.
Reversible dinitrogen binding to [Cp'Fe(NHC)] associated with an N2-induced spin state change.
复制标题
DOI：
10.1039/c7cc01535f
复制
发表时间：
2017-06
影响因子：
4.9
通讯作者：
Matthias Reiners;D. Baabe;Marc-Kevin Zaretzke;M. Freytag;Marc D. Walter
中科院分区：
文献类型：
--
作者：
Matthias Reiners;D. Baabe;Marc-Kevin Zaretzke;M. Freytag;Marc D. Walter
15 价电子 (VE)、高自旋 (S = 3/2) 半夹心配合物 [Cp'Fe(IiPr2Me2)] (3; IiPr2Me2 = 1,3-二异-丙基-4,5-二甲基咪唑-2-亚基) 可逆配位 N2 形成 17VE、低自旋 (S = 1/2) 化合物[Cp'Fe(IiPr2Me2)(η1-N2)] (4)。
The 15-valence electron (VE), high-spin (S = 3/2) half-sandwich complex [Cp'Fe(IiPr2Me2)] (3; IiPr2Me2 = 1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene) reversibly coordinates N2 to form the 17VE, low-spin (S = 1/2) compound [Cp'Fe(IiPr2Me2)(η1-N2)] (4).