The chemistry of the actinide and transactinide elements
The chemistry of the actinide and transactinide elements
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DOI：
10.1007/978-94-007-0211-0
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发表时间：
2006
期刊：
影响因子：
--
通讯作者：
L. Morss;N. Edelstein;J. Fuger
中科院分区：
文献类型：
--
作者：
L. Morss;N. Edelstein;J. Fuger
第四版“锕系元素和跨锕系元素的化学”包括第三版（2006年出版）的第1卷到第5卷中的所有章节以及新的第6卷。为了与第一版的计划保持一致，“……为核技术专家以及无机和物理化学家提供锕系元素[和转锕系元素]化学的全面和统一的处理”，并与该领域的成熟度保持一致，第四版被组织成三个部分。第一组章节遵循第一版和第二版的格式，其中有关于单个元素或元素组的章节，描述和解释它们的化学性质。下面是关于锕系元素的化学性质的一章。第二组，15-26章，总结并关联了锕系元素通常特有的物理和化学性质，因为这些元素中的大多数都含有部分填充的5f电子壳层，无论是作为孤立的原子或离子，作为金属，作为化合物，还是作为溶液中的离子。第三组，第27-39章，侧重于包括与环境、人体、储存或废物中的锕系元素相关的当代领域的专门主题。第5卷末尾的两个附录列出了所有锕系元素和转锕系元素同位素的重要核性质。第6卷（第32章至第39章）增加了新的章节，重点介绍环境中的锕系元素、锕系元素废物形式、核燃料、钚的分析化学、锕系元素硫属化物和锕系元素化合物的水热合成。主题和作者索引以及贡献者名单涵盖了所有六卷。
The fourth edition of" The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition,“… to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts.The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements containpartially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.