Regioselective nitration of naphthalene over HZSM-5-supported phosphotungstic acid

Regioselective nitration of naphthalene over HZSM-5-supported phosphotungstic acid
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HZSM-5 负载磷钨酸对萘的区域选择性硝化

DOI:
10.1007/s11164-014-1549-1
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发表时间:
2015-07
期刊:
Res Chem Intermed
影响因子:
--
通讯作者:
He’an Luo
He’an Luo
中科院分区:
其他
文献类型:
--
作者:
Kun Huang;Fang Hao;Liangjie Wang;He’an Luo

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HZSM-5-supported phosphotungstic acid (PW) has been prepared and characterized. The results indicate that 5 wt% PW/HZSM-5 calcined at 773 K has the largest surface area and high dispersion of PW. It was confirmed that Keggin units are present inside the catalyst and that the proton of PW and the silanol of HZSM-5 interact via bridging structure. The catalytic properties of PW/HZSM-5 in the regioselective nitration of naphthalene to dinitronaphthalene were investigated. The best results, i.e. 48.5 % yield of 1,5-dinitronaphthalene, 49.2 % yield of 1,8-dinitronaphthalene, and the highest ratio of 1,5-dinitronaphthalene to 1,8-dinitronaphthalene, were obtained by use of 5 wt% PW/HZSM-5.
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