Redox-switchable molecular containers consisting of dicobalt complexes.
Redox-switchable molecular containers consisting of dicobalt complexes.
复制标题
DOI：
10.1021/ic051482o
复制
发表时间：
2005-12
影响因子：
4.6
通讯作者：
H. Shimakoshi;T. Takemoto;Isao Aritome;Y. Hisaeda
中科院分区：
文献类型：
--
作者：
H. Shimakoshi;T. Takemoto;Isao Aritome;Y. Hisaeda
合成了双齿二胺双桥双钴配合物，并用x射线衍射对其进行了表征。利用循环伏安法和紫外可见法研究了Co（II）和Co（III）之间的氧化还原偶对双桥结构的可逆形成和分解。
Doubly bridged dicobalt complexes with bidentate diamine ligands were synthesized and characterized by X-ray diffraction studies. Reversible formation and decomposition of the doubly bridged structure utilizing the redox couple between Co(II) and Co(III) were investigated by cyclic voltammetry and UV-vis.