The expanding field of polyphosphazene high polymers
The expanding field of polyphosphazene high polymers
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DOI：
10.1039/c5dt03887a
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发表时间：
2016-01-01
影响因子：
4
通讯作者：
Allcock, Harry R.
中科院分区：
文献类型：
--
作者：
Allcock, Harry R.
磷在聚合物化学中的重要性由聚磷腈科学的广泛领域的发展来说明。现在已知有几百种高聚物具有磷氮骨架和250多种不同的有机侧基的组合。这些聚合物的性质取决于无机主链的性质和有机侧基的结构。本文综述了这些材料的合成途径，通常独特的结构性质关系，以及该领域未来扩展的挑战。
The importance of phosphorus in polymer chemistry is illustrated by the growth of the broad field of polyphosphazene science. Several hundred high polymers are now known with a phosphorus-nitrogen backbone and combinations or more than 250 different organic side groups. The properties of these polymers depend on both the character of the inorganic backbone and the structure of the organic side groups. This summary reviews the synthesis pathways to these materials, the often-unique structure property relationships, and challenges for the future expansion of this field.