Metal-catalysed cleavage of carbon-carbon bonds
Metal-catalysed cleavage of carbon-carbon bonds
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DOI：
10.1039/c0cc02566f
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Matsuda, Takanori
中科院分区：
文献类型：
--
作者：
Murakami, Masahiro;Matsuda, Takanori
在过渡金属催化剂的帮助下，裂解碳-碳键的反应提供了各种难以实现的分子转化，为有机合成开辟了一条沿着的风景大道。在过去的十年中，结构基序如中等大小的碳环和手性季碳中心的构建已经被设置在这种矛盾的方法的访问范围内。
Reactions cleaving carbon-carbon bonds with the assistance of transition metals as the catalyst have provided various molecular transformations that are otherwise difficult to execute, opening a scenic avenue along organic synthesis. Construction of structural motifs like medium-sized carbocycles and chiral quaternary carbon centres have been set within an access of such paradoxical approaches in the past decade.