The total synthesis of (±)-11-O-Debenzoyltashironin
The total synthesis of (±)-11-O-Debenzoyltashironin
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DOI：
10.1021/ja0670254
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发表时间：
2006-12-27
影响因子：
15
通讯作者：
Danishefsky, Samuel J.
中科院分区：
文献类型：
--
作者：
Cook, Silas P.;Polara, Alessandra;Danishefsky, Samuel J.
The total synthesis of the putative non-peptidyl neurotrophic factor 11-O-debenzoyltashironin has been accomplished. The key transformation involves a biomimetic oxidative dearomatization/transannular Diels−Alder sequence that closes the tetracyclic carbon skeleton present in the natural product.
