A novel, facile route to β-fluoroamines by hydrofluorination using superacid HF-SbF5
A novel, facile route to β-fluoroamines by hydrofluorination using superacid HF-SbF5
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DOI：
10.1039/b703629a
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Zunino, Fabien
中科院分区：
文献类型：
--
作者：
Thibaudeau, Sebastien;Martin-Mingot, Agnes;Zunino, Fabien
基于高反应性亲电中间体的形成，一系列不饱和胺和磺酰胺在超强酸 HF-SbF5 中氢氟化后转化为 β-氟氮类似物。
A range of unsaturated amines and sulfonamides were converted to beta-fluoro nitrogen analogues after hydrofluorination in superacid HF-SbF5, based on the formation of highly reactive electrophilic intermediates.