A novel photoluminescent Ag-terpyridyl complex: one-dimensional linear metal string with double-helical structure

A novel photoluminescent Ag-terpyridyl complex: one-dimensional linear metal string with double-helical structure
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一种新型光致发光银-三联吡啶配合物:具有双螺旋结构的一维线性金属串

DOI:
10.1016/j.inoche.2004.11.019
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发表时间:
2005-01-01
影响因子:
3.8
通讯作者:
Li, D
Li, D
中科院分区:
化学4区
文献类型:
--
作者:
Hou, L;Li, D

文献摘要

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合成了一种新型的双螺旋荧光配合物[Ag 4L 4](PF 6)(4)(.)(CH_3COCH_3)(2)(1)(L = 4 ′-苯基-2,2 ′:6 ′,2 ″-三联吡啶)的合成和结构表征。亲铁性(配体支持和非支持的Ag…2.8441-3.215埃的Ag接触)在确定无限金属弦和发光性质方面起着重要作用。(C)2004 Elsevier B. V.保留所有权利。
A novel photoluminescent double-helical complex, [Ag4L4](PF6)(4) (.) (CH3COCH3)(2) (1) (L = 4'-phenyl-2,2':6',2"-terpyridine) was synthesised and structurally characterised. Argentophilicity (ligand-supported and -unsupported Ag... Ag contacts of 2.8441-3.215 Angstrom) plays an important role in determining the infinite metal string and the nature of luminescence. (C) 2004 Elsevier B.V. All rights reserved.