Cu(OTf)2 catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: rapid construction of the yuremamine core
Cu(OTf)2 catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: rapid construction of the yuremamine core
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DOI：
10.1039/c3cc40617b
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Das, Saikat
中科院分区：
文献类型：
--
作者：
Dethe, Dattatraya H.;Boda, Raghavender;Das, Saikat
刘易斯酸催化[6+2]环加成反应合成吡咯[1,2-a]吲哚，以高度区域和非对映选择性的方式生成三个连续的立体中心，并进一步应用于构建全功能化的氨基三环核心。
Lewis acid catalysed [6+2] cycloaddition reaction for the synthesis of pyrrolo[1,2-a] indoles generating three contiguous stereocenters in a highly regio-and diastereoselective manner has been developed and further applied for the construction of the fully functionalized tricyclic core of yuremamine.