Good dispersion of hydrophilic nanoscale silica in rubber matrix and the effects on rubber nanocomposites

Good dispersion of hydrophilic nanoscale silica in rubber matrix and the effects on rubber nanocomposites
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亲水性纳米二氧化硅在橡胶基体中的良好分散性及其对橡胶纳米复合材料的影响

DOI:
10.1007/s11431-011-4709-1
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发表时间:
2012-01
期刊:
SCIENCE CHINA Technological Sciences
影响因子:
--
通讯作者:
ZHANG XiaoHong
ZHANG XiaoHong
中科院分区:
其他
文献类型:
--
作者:
ZHANG LiQun;SONG ZhiHai;QIAO JinLiang;WANG QingGuo,;XIE JingHui;ZHANG XiaoHong

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Using the industrial technologies of rubber latex irradiation, preparation of nanoscale silica (SiO2) slurry, mixing irradiated rubber latex with SiO2slurry, and the spray drying, we have prepared the ultrafine fully-vulcanized powder carboxyl styrene-butadiene rubber (UFPCSBR)/SiO2nanocompound powder, in which the SiO2particles and UFPCSBR particles are isolated and stuck each other. When the UFPCSBR/SiO2nanocompound powder is mixed with crude rubber, the UFPCSBR particles are dispersed well in rubber matrix because of their good compatibility, then the SiO2particles are also dispersed well in rubber matrix because of the carrier nature of the UFPCSBR particles during the mixing procedure, and the novel rubber/UFPCSBR/SiO2nanocomposites are fabricated. Compared with the rubber composites prepared by mixing the crude rubber with the UFPCSBR powder and SiO2powder one after the other, the novel UFPCSBR/SiO2nanocompound modified rubber/ UFPCSBR/SiO2nanocomposites have better abrasion resistance, higher tensile strength and tear strength, and lower heat build-up data. Noteworthily, the tanδ-temperature curve of the novel rubber/UFPCSBR/SiO2nanocomposites has the second tanδpeak due to the newly generated boundary layer surrounding the SiO2particles, increasing the tanδvalues in the temperature range of 0–20°C, which is very important to the research of green tyre tread.
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