Directing the reactivity of [HFe4N(CO)12]- toward H+ or CO2 reduction by understanding the electrocatalytic mechanism.
Directing the reactivity of [HFe4N(CO)12]- toward H+ or CO2 reduction by understanding the electrocatalytic mechanism.
复制标题
通过了解电催化机制，指导 [HFe4N(CO)12]- 的反应活性以还原 H 或 CO2。
DOI：
10.1021/ja208312t
复制
发表时间：
2011
影响因子：
15
通讯作者：
Louise A. Berben
中科院分区：
文献类型：
--
作者：
M. Rail;Louise A. Berben
电催化生成的催化剂-氢化物中间体对析氢反应（HER）或CO(2)还原的选择性反应性是CO(2)还原电催化剂的关键。在适当的条件下，Et(4)N[Fe(4)N(CO)(12)] （Et(4)N-1）是在-1.25 V vs SCE下使用玻碳电极进行HER或CO(2)转化的催化剂。
Selective reactivity of an electrocatalytically generated catalyst-hydride intermediate toward the hydrogen evolution reaction (HER) or reduction of CO(2) is key for a CO(2) reduction electrocatalyst. Under appropriate conditions, Et(4)N[Fe(4)N(CO)(12)] (Et(4)N-1) is a catalyst for the HER or for CO(2) conversion at -1.25 V vs SCE using a glassy carbon electrode.