Preparation of glass-like carbon with micrometer-sized pores by mixing thermosetting resin with thermoplastic microbeads

Preparation of glass-like carbon with micrometer-sized pores by mixing thermosetting resin with thermoplastic microbeads
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热固性树脂与热塑性微珠混合制备微米级孔玻璃状碳

DOI:
10.1016/j.matlet.2022.131691
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发表时间:
2022
期刊:
影响因子:
3
通讯作者:
Horibe Ryuto
Horibe Ryuto
中科院分区:
材料科学3区
文献类型:
--
作者:
Nakamura Kazumasa;Kubo Chiemi;Horibe Ryuto

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类玻璃碳(Glass-like Carbon,GLC)是一种非颗粒状的碳材料,其表面和断裂面具有类玻璃的外观。在本研究中,通过将热固性树脂与两种尺寸的热塑性微球混合,制备了具有大量微米级孔径的凝胶电致发光材料。对于这些凝胶载体,当它们与微球混合时,碳化产率和表观密度降低。扫描电子显微镜结果表明,与大颗粒制备的凝胶复合材料相比,掺入小颗粒的凝胶载体表面和断口具有更小的孔径。经1000℃或以上热处理的含小珠的凝胶电致发光材料的电阻与纯净的凝胶电致发光材料相比几乎没有变化。
Glass-like carbon (GLC) is an agranular carbon material with a pseudo-glass-like appearance on the surface and fractured face. In this study, GLCs with numerous micrometer-sized pores were prepared by mixing thermosetting resins with two sizes of thermoplastic microbeads. For these GLCs, the carbonization yields and apparent densities decreased when they were mixed with microbeads. SEM results suggested that the surfaces and fracture faces of GLCs mixed with small beads possess smaller pores compared to those prepared with large beads. The electrical resistances of GLCs with small beads heat-treated at 1000 ℃ or above were almost unchanged compared to those of the neat GLCs.
1200~3000℃热处理的类玻璃碳在干燥空气下500℃表面氧化行为分析
DOI: --
发表时间: 2009
期刊:
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作者:
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