A GENERALIZATION OF RETENTION INDEX SYSTEM INCLUDING LINEAR TEMPERATURE PROGRAMMED GAS-LIQUID PARTITION CHROMATOGRAPHY

A GENERALIZATION OF RETENTION INDEX SYSTEM INCLUDING LINEAR TEMPERATURE PROGRAMMED GAS-LIQUID PARTITION CHROMATOGRAPHY
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DOI:
10.1016/s0021-9673(01)80947-x
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发表时间:
1963-01-01
期刊:
JOURNAL OF CHROMATOGRAPHY
影响因子:
--
通讯作者:
KRATZ, PD
KRATZ, PD
中科院分区:
其他
文献类型:
--
作者:
VANDENDOOL, H;KRATZ, PD

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综述了描述色谱峰位置的不同方法。保留指数优于理论体系和相对保留率。将Kovats给出的等温操作条件下的保留指数计算公式转换为更一般的形式,以包括线性程序升温操作的情况。这一广义方程为两种操作方式提供了相同的保留指数。
The different ways of describing peak positions on gas chromatograms are reviewed. The retention index is preferred to the theoretical nonane system and the relative retention. The equation given by KOVATS for the calculation of the retention index in case of isothermal operation is transformed to a more general form to include also the case of linear temperature programmed operation. This generalized equation gives the same retention index for both ways of operation.