High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal Organic Framework
High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal Organic Framework
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令人着迷的基于纳米管的金属有机框架具有高二氧化碳吸收能力和选择性
DOI：
10.1021/acs.inorgchem.6b02491
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发表时间：
2017
影响因子：
4.6
通讯作者：
Wang Yao-Yu
中科院分区：
文献类型：
--
作者：
Wu Yun-Long;Qian Jinjie;Yang Guo-Ping;Yang Fan;Liang Yu-Tong;Zhang Wen-Yan;Wang Yao-Yu
以Pb（II）和刚性的V型4，4 ′-（吡啶-3，5-二基）二甲酸（H4 L）为原料，合成了一种特殊的多孔金属有机骨架.结构分析表明，纳米管骨架中存在14.26 × 10.69 × 10.69 × 10.63纳米管。纳米多孔MOF的气体吸附行为显示出相对于CH 4的CO2的相对高的容量和选择性。
An unusual porous metal–organic framework has been synthesized by using Pb(II) and rigid V-shaped 4,4′-(pyridine-3,5-diyl)diisophthalic acid (H4L). Structure analysis reveals that there exist 1D cylindrical 14.26 Å and triangular prism 10.69 × 10.69 × 10.69 Å3nanotubes in the framework. Gas sorption behavior of the nanoporous MOF shows a relatively high capacity and selectivity of CO2over CH4.