Highly enantiomeric supramolecular [4+4] photocyclodimerization of 2-anthracenecarboxylate mediated by human serum albumin
Highly enantiomeric supramolecular [4+4] photocyclodimerization of 2-anthracenecarboxylate mediated by human serum albumin
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DOI：
10.1021/ja068475z
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发表时间：
2007-03-28
影响因子：
15
通讯作者：
Inoue, Yoshihisa
中科院分区：
文献类型：
--
作者：
Nishijima, Masaki;Wada, Takehiko;Inoue, Yoshihisa
在λ> 320 nm的光照射下，在5 ℃的缓冲水溶液中与人血清白蛋白结合的2-蒽甲酸酯得到82%ee的顺式头-尾环二聚体2和90%ee的反式头-头环二聚体3。
Photoirradiation at lambda > 320 nm of 2-anthracenecarboxylate bound to human serum albumin in an aqueous buffer solution at 5 degrees C gave syn head-to-tail cyclodimer 2 in 82% ee and anti head-to-head cyclodimer 3 in 90% ee.