Spin crossover complex film, [FeII(H-trz)3]-nafion, with a spin transition around room temperature
Spin crossover complex film, [FeII(H-trz)3]-nafion, with a spin transition around room temperature
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DOI：
10.1246/cl.2003.336
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发表时间：
2003-04-05
影响因子：
1.6
通讯作者：
Yokoyama, T
中科院分区：
文献类型：
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作者：
Nakamoto, A;Ono, Y;Yokoyama, T
我们用离子交换树脂(Nafion)作为反阴离子合成了[Fe-II(H-TRZ)(3)](N)络合物薄膜，在260K附近发现了自旋交叉现象，并用EXAFS证明了[Fe-II(H-TRZ)(3)](N)在Nafion上存在一维直线铁链结构。
We have synthesized [Fe-II(H-trz)(3)](n) complex film by using ion-exchange resin(Nafion) as counter anion, and have found the spin crossover phenomenon about at 260 K. Moreover, we have proved the existence of straight one-dimensional Fe chain structure of [Fe-II(H-trZ)(3)](n) on Nafion by means of EXAFS.