Hydrotelluration of aminoalkynes.
Hydrotelluration of aminoalkynes.
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DOI:
10.1039/b301857a
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发表时间:
2003-05
影响因子:
4.9
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中科院分区:
文献类型:
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Metal tellurolates (M = B3+; BuTeTeBu/NaBH4/EtOH; Li3+, Te0/BuLi/THF; In3+, BuTeTeBu/InI/EtOH) react with aminoalkynes to produce vinylic tellurides containing amino groups; the regio-, and stereo-chemistry of the hydrotelluration reaction depend on the metallic counter ion and on the nature of the amino group substituent.