Comparative study of photobleachable polysilane copolymers applied to optical waveguides

Comparative study of photobleachable polysilane copolymers applied to optical waveguides
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应用于光波导的光漂白聚硅烷共聚物的比较研究

DOI:
10.1016/j.optmat.2010.10.016
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发表时间:
2011
期刊:
影响因子:
3.9
通讯作者:
Mamoru Iso
Mamoru Iso
中科院分区:
材料科学3区
文献类型:
--
作者:
Lei He;Baoxue Chen;Mamoru Iso

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以PMPS为大分子光自由基引发剂,通过光聚合制备了三种不同的共聚物:聚甲基苯基硅烷-聚甲基丙烯酸甲酯(PMPS-PMMA)、PMPS-聚(苯乙烯)(PMPS-PS)和PMPS-聚(甲基丙烯酸苄酯)(PMPS-PBzMA)。对于光波导的制造,对其紫外光谱、光漂白、折射率变化和光学性能进行了比较研究。此外,使用这些共聚物成功地制造了通道波导,并报道了它们的光学传播性能,结果表明它们是光波导应用的潜在材料。
Three different copolymers, poly(methylphenylsilane)–poly(methylmethacrylate) (PMPS–PMMA), PMPS–poly(styrene) (PMPS–PS), and PMPS –poly(benzylmethacrylate) (PMPS–PBzMA), were prepared by photopolymerization using PMPS as a macromolecular photo-radical initiator. For optical waveguide fabrication, their UV spectra, photobleaching, refractive index change and optical properties were comparatively investigated. Furthermore, channel waveguides were successfully fabricated using these copolymers and their optical propagation properties were reported, the results indicate that they are potential materials for optical waveguide applications.
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