Trigonal prismatic Cu(I) and Ag(I) pyrazolato nanocage hosts: encapsulation of S8 and hydrocarbon guests
Trigonal prismatic Cu(I) and Ag(I) pyrazolato nanocage hosts: encapsulation of S8 and hydrocarbon guests
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三棱柱形 Cu(I) 和 Ag(I) 吡唑纳米笼主体：S8 和烃类客体的封装
DOI：
10.1039/c3dt51332g
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发表时间：
2013-01-01
影响因子：
4
通讯作者：
Raptis, Raphael G.
中科院分区：
文献类型：
--
作者：
Duan, Peng-Cheng;Wang, Zhao-Yang;Raptis, Raphael G.
通过将两个平面三角形的M（3）pz（3）-嵌段，M = Cu（I）和Ag（I）以重叠几何构型偶联，合成了两个中性的六核三角棱柱笼状分子.类似于230埃（3）的笼体积可以是空的或由中性客人占据。测定了M-6-环己烷和Ag-6-S-8主客体的晶体结构。
Two neutral hexanuclear trigonal prismatic cage molecules have been synthesized by coupling two planar triangular M(3)pz(3)-panels, M = Cu(I) and Ag(I), in eclipsed geometry. The similar to 230 angstrom(3) cage volume can be either vacant or occupied by neutral guests. The crystal structures of the M-6-cyclohexane and Ag-6-S-8 host-guest species have been determined.