Retention and selectivity in carbon dioxide supercritical fluid chromatography with various stationary phases
Retention and selectivity in carbon dioxide supercritical fluid chromatography with various stationary phases
复制标题
具有各种固定相的二氧化碳超临界流体色谱的保留和选择性
DOI：
10.1016/s0021-9673(01)87077-1
复制
发表时间：
1986
影响因子：
4.1
通讯作者：
R. Rosset
中科院分区：
文献类型：
--
作者：
P. Mourier;P. Sassiat;M. Caude;R. Rosset
本文研究了CO2超临界流体色谱中各种参数对溶质保留的影响。考察了极性改性剂对裸硅胶、十八烷基键合硅胶和“吡”键合硅胶三种固定相的影响。手性键合固定相上的对映体分离是超临界流体色谱的一个有趣的应用。一些膦氧化物已被拆分，并与手性键合固定相进行了比较。
A study has been conducted on the influence of various parameters on solute retention in supercritical fluid chromatography (SFC) with carbon dioxide,The influence of polar modifier addition to carbon dioxide has been studied on three stationary phases: bare silica, octadecyl-bonded silica and “PirEnantiomeric separation on a chiral-bonded stationary phase constitutes an interesting application of SFC. Some phosphine oxides have been resolved, wi