The carbon-13 and phosphorus-31 nuclear magnetic resonance spectra of some tertiary phosphines

The carbon-13 and phosphorus-31 nuclear magnetic resonance spectra of some tertiary phosphines
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部分叔膦的碳13和磷31核磁共振谱

DOI:
10.1039/p29720000030
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发表时间:
1972
期刊:
Journal of The Chemical Society-perkin Transactions 1
影响因子:
--
通讯作者:
B. Mann
B. Mann
中科院分区:
--
文献类型:
--
作者:
B. Mann

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31P和13C n.m.r.报道了一些叔膦的光谱。影响化学位移和耦合常数的因素进行了检查,并建议,参与确定从一个叔膦到另一个的化学位移的变化的主要因素是在有关的核的键角。
The 31P and 13C n.m.r. spectra for some tertiary phosphines are reported. Factors affecting the chemical shifts and coupling constants are examined, and it is suggested that the major factor involved in determining changes in chemical shifts from one tertiary phosphine to another is the bond angle at the nucleus concerned.