Metal-free carbon-nitrogen bond-forming coupling reaction between arylboronic acids and organic azides
Metal-free carbon-nitrogen bond-forming coupling reaction between arylboronic acids and organic azides
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DOI：
10.1016/j.tetlet.2010.11.103
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发表时间：
2011-03-30
影响因子：
1.8
通讯作者：
Yu, Yongping
中科院分区：
文献类型：
--
作者：
Ou, Lili;Shao, Jiaan;Yu, Yongping
报道了一种新型高效的芳基硼酸与有机叠氮化合物之间的无金属碳氮键偶联反应。该反应对于制备仲芳胺是相当普遍的。此外，该反应对官能团具有很强的耐受性。并提出了一种可能的机制。(C)2011爱思唯尔有限公司。保留所有权利。
A novel and efficient metal-free carbon-nitrogen bond-forming coupling reaction between arylboronic acids and organic azides is reported. The reaction is fairly general for the preparation of secondary aromatic amines. Furthermore, the reaction is very functional-group tolerant. A possible mechanism is also proposed. (c) 2011 Elsevier Ltd. All rights reserved.