Catalytic Deoxydehydration of Glycols with Alcohol Reductants
Catalytic Deoxydehydration of Glycols with Alcohol Reductants
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DOI：
10.1002/cssc.201200781
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发表时间：
2013-04-01
期刊：
影响因子：
8.4
通讯作者：
Nicholas, Kenneth M.
中科院分区：
文献类型：
--
作者：
Boucher-Jacobs, Camille;Nicholas, Kenneth M.
顶层架脱水：与苄醇还原剂组合的过氧化铵催化剂用于二醇到烯烃的有效脱氧脱水。烯烃和醛产物可以容易地分离和离析。由于该催化剂在芳烃溶剂中的溶解度低，可以回收再利用。
Top shelf dehydration: Ammonium perrhenate catalysts combined with benzylic alcohol reductants are used for the efficient deoxydehydration of glycols to olefins. The olefin and aldehyde products can be easily separated and isolated. It is also demonstrated that the catalyst can be recovered and reused because of its low solubility in aromatic solvents.