Synthesis and Structure of 16 π Octaalkyltetraphenylporphyrins
Synthesis and Structure of 16 π Octaalkyltetraphenylporphyrins
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DOI：
10.1021/ja052842
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发表时间：
2005-09
影响因子：
15
通讯作者：
Yohsuke Yamamoto;A. Yamamoto;S. Furuta;M. Horie;M. Kodama;Wataru Sato;K. Akiba;S. Tsuzuki;T. Uchimaru;D. Hashizume;F. Iwasaki
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文献类型：
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作者：
Yohsuke Yamamoto;A. Yamamoto;S. Furuta;M. Horie;M. Kodama;Wataru Sato;K. Akiba;S. Tsuzuki;T. Uchimaru;D. Hashizume;F. Iwasaki
从OETPPLi_2（或OisoBuTPPLi_2）与SOCl_2的反应中分离得到氧化的八乙基四苯基卟啉（1，OETPP）和相应的新合成的八异丁基四苯基卟啉（3，OisoBuTPP）。X射线衍射分析和特征紫外-可见光谱表明，1和3是16 π非芳香卟啉的第一个例子。
The oxidized octaethyltetraphenylporphyrin (1, OETPP) and the corresponding newly prepared octaisobutyltetraphenylporphyrin (3, OisoBuTPP) could be isolated from the reaction of OETPPLi2 (or OisoBuTPPLi2) with SOCl2. The X-ray analysis and the characteristic UV-vis spectra of 1 and 3 revealed that these are the first examples of 16 pi nonaromatic porphyrins.