Phase Diagrams for Geoscientists
Phase Diagrams for Geoscientists
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DOI：
10.1007/978-3-540-38352-9
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发表时间：
2003-04
影响因子：
5.3
通讯作者：
T. Gasparik
中科院分区：
文献类型：
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作者：
T. Gasparik
本书总结了作者在1979年至2001年的20多年时间里对与地球有关的化学系统中的相关系进行的实验研究的结果。它是基于1，000个压力高达4 GPa的活塞气缸实验和近700个压力高达24 GPa的多砧装置进行的实验。这些研究的重点是内部一致性。大量的数据是使用相同的样品组件，高压装置，实验程序和校准由同一实验人员，以最大限度地提高内部一致性。研究结果发表在书末列出的70篇同行评议文章中。这些都是引用只有相应的数字，而完整的参考是为所有其他来源。在这些研究的早期，显然需要一个总结，可能是一本书的形式，因为在工作仍在进行中的时候，不可能在内部一致的热力学模型框架内发表单独研究项目的中间结果。因此，这本书准备了近20年。除了作者所产生的数据外，这本书还总结了许多其他实验岩石学家在上个世纪后半叶进行的高压和高温下的研究。如果没有基础研究资助机构，特别是美国国家科学基金会的慷慨资助，这些研究是不可能的。不幸的是，实验岩石学，特别是相平衡研究的资金一直在下降，这一领域的机会之窗可能已经关闭。几个关键的发展是必不可少的这项工作，如发明的活塞缸和多砧装置，以实现高压，相应的实验技术的发展，发明的电子探针的实验产品的分析，发明的个人电脑和进步，提高其计算速度，最后开发文字处理（Microsoft Word）和图形设计（Micrografx Designer 7）软件。因此，回想起来，这是相当幸运的，所有这些都在正确的时间和正确的顺序走到一起，使这本书在2003年出版成为可能。
This book summarizes the results of the experimental studies of phase relations in the chemical systems relevant to Earth, carried out by the author in a time period of over 20 years between 1979 and 2001. It is based on 1,000 pistoncylinder experiments at pressures up to 4 GPa and close to 700 experiments carried out with a multi-anvil apparatus at pressures up to 24 GPa. The emphasis in these studies was on internal consistency. Large sets of data were produced using the same sample assembly, high-pressure apparatus, experimental procedures and calibrations by the same experimentalist to maximize the internal consistency. The results were published in 70 peer-reviewed articles listed at the end of the book. These are referenced only by the corresponding number, while the full reference is given for all other sources. The need for a summary, possibly in the form of a book, had become evident early on in the course of these studies, since it was impossible to publish intermediate results of separate research projects within the framework of an internally consistent thermodynamic model, while the work was still in progress. Hence, this book was in preparation for almost 20 years. In addition to the data produced by the author, the book summarizes also the research at high pressures and temperatures carried out mostly in the second half of the last century by many other experimental petrologists. These studies would not have been possible without the generous financial support by the funding agencies for basic research, particularly the National Science Foundation of the United States government. Unfortunately, the funding for the experimental petrology, and particularly the phase equilibrium studies, has been in decline, and the window of opportunity in this field may have already closed. Several crucial developments were essential for this work, such as the invention of the piston-cylinder and multi-anvil devices for achieving high pressures, the development of the corresponding experimental techniques, the invention of the electron microprobe for the analysis of the experimental products, the invention of the personal computer and the progress in increasing its computing speed, and finally the development of the word processing (Microsoft Word) and the graphics design (Micrografx Designer 7) software. Hence, in retrospect, it is quite fortunate that all this came together in the right sequence and at the right time to make the publication of this book in 2003 possible.