Effect of annealing temperature on surface morphology and work function of ZnO nanorod arrays

Effect of annealing temperature on surface morphology and work function of ZnO nanorod arrays
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退火温度对ZnO纳米棒阵列表面形貌和功函数的影响

DOI:
10.1016/j.jallcom.2013.02.172
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发表时间:
2013-07-15
影响因子:
6.2
通讯作者:
Li, Wen
Li, Wen
中科院分区:
材料科学2区
文献类型:
--
作者:
Wu, Hainan;Xue, Mingshan;Li, Wen

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A simple and effective method of fabricating nanomaterials and the understanding of their electronic structures are significant for designing novel nanodevices. In this study, ZnO nanorod arrays on ITO substrate were synthesized by electrochemical deposition, and the effect of annealing temperature on surface morphology and especially work function was investigated using various techniques. The results indicated that the formation of hexagonal ZnO nanorod arrays with (0001) orientation was strongly associated with the annealing temperature. The work function of well-aligned ZnO nanorod arrays is 4.84 eV, which shows an obvious dependence on the arrangement of ZnO nanorod arrays. These changes in work function of ZnO nanorod arrays (e.g., used as the photoanode of dye-sensitized solar cells) are important to understand the electron transport of related nanodevices. (C) 2013 Elsevier B.V. All rights reserved.