METAL AMINE COORDINATION COMPOUNDS .1. COPPER (II) COMPLEXES
METAL AMINE COORDINATION COMPOUNDS .1. COPPER (II) COMPLEXES
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DOI：
10.1021/ja01653a001
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发表时间：
1954-01-01
影响因子：
15
通讯作者：
BRANDT, WW
中科院分区：
文献类型：
--
作者：
PFLAUM, RT;BRANDT, WW
一些胺络合物的铜（II）离子的性质进行了研究。收集了一系列多胺配合物的吸光数据。研究了吡啶、非水溶剂和还原剂对配位金属胺的影响。确定了铜与1，10-邻菲咯啉、2，2 ′-联吡啶和2，2 ′，2 ″-三联吡啶配合物的分子式，并测定了配合物随体系pH值的变化。从电位数据计算铜（II）-1，10-菲咯啉络合物的稳定常数的值。研究的金属胺的性质和行为的相关性的基础上，在配位试剂的变化。
A study of the nature of some of the amine complexes of the copper (II) ion was carried out. Absorptimetric data were compiled for a series of polyamine coordination compounds. The effects of pñ, non-aqueous solvents and reducíants on the coordinated metal amines were determined. Formulas for the complexes of copper with 1, 10-phenanthroline, 2, 2'-bipyridine and 2, 2', 2"-terpyridine were determined together with the changes in coordination with variations in the pH of the systems. A value for the stability constant for the copper (II)-l, 10-phenanthroline complex was calculated from potentiometric data. A correlation of the nature and behavior of the metal amines studied was made on the basis of variations in the coordinating reagents.