Surface-Supported, Highly Ordered Macroporous Crystalline TiO2 Thin Films Robust up to 1000°C

Surface-Supported, Highly Ordered Macroporous Crystalline TiO2 Thin Films Robust up to 1000°C
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DOI:
10.1021/cm703669d
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发表时间:
2008-11-11
影响因子:
8.6
通讯作者:
Gutmann, Jochen S.
Gutmann, Jochen S.
中科院分区:
材料科学2区
文献类型:
--
作者:
Cheng, Ya-Jun;Zhi, Linjie;Gutmann, Jochen S.

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以PEO-PS-PEO三嵌段共聚物为模板剂,采用良-贫溶剂对诱导相分离和溶胶-凝胶化学方法制备了大孔TiO 2薄膜。大孔TiO 2在高达至少1000 °C下表现出不寻常的热结构稳定性。
Macroporous crystalline TiO2thin film is achieved by using an amphiphilic triblock copolymer of PEO-PS-PEO as a templating agent, coupled with a good-poor solvent pair induced phase separation process and sol−gel chemistry. The macroporus TiO2exhibits unusual thermal structural stability up to at least 1000 °C.