Solid-state NMR spectroscopy of molecular hydrogen trapped inside an open-cage fullerene

Solid-state NMR spectroscopy of molecular hydrogen trapped inside an open-cage fullerene
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DOI:
10.1021/ja031536y
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发表时间:
2004-04-07
影响因子:
15
通讯作者:
Levitt, MH
Levitt, MH
中科院分区:
化学1区
文献类型:
--
作者:
Carravetta, M;Murata, Y;Levitt, MH

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固态1H实验进行了开笼富勒烯托管分子氢。用双量子魔角自旋核磁共振研究了氢分子转动的各向异性。氢分子旋转的时间尺度估计作为温度的函数的自旋-晶格弛豫测量。
Solid-state1H experiments were performed an open-cage fullerene hosting molecular hydrogen. The anisotropy of the molecular hydrogen rotation was studied by double-quantum magic-angle-spinning NMR. The time scale of the molecular hydrogen rotation was estimated by spin-lattice relaxation measurements as a function of temperature.