A Two-Dimensional Polymer from the Anthracene Dimer and Triptycene Motifs
A Two-Dimensional Polymer from the Anthracene Dimer and Triptycene Motifs
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DOI：
10.1021/ja404351p
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发表时间：
2013-09-25
影响因子：
15
通讯作者：
King, Benjamin T.
中科院分区：
文献类型：
--
作者：
Bhola, Radha;Payamyar, Payam;King, Benjamin T.
报道了一种基于三蝶烯基序中蒽并基团二聚化的二维聚合物（2DP）。光诱导聚合在结晶状态下进行，并通过晶体到晶体（但不是单晶到单晶）转化得到层状2DP。溶剂诱导的剥落提供了2DP的单层片。2DP被认为是一种平铺，一种促进结构解析的数学方法。
A two-dimensional polymer (2DP) based on the dimerization of anthraceno groups arranged in a triptycene motif is reported. A photoinduced polymerization is performed in the crystalline state and gives a lamellar 2DP via a crystal-to-crystal (but not single-crystal to single-crystal) transformation. Solvent-induced exfoliation provides monolayer sheets of the 2DP. The 2DP is considered to be a tiling, a mathematical approach that facilitates structural elucidation.