Driving dimethyl carbonate synthesis from CO2 and methanol and production of acetylene simultaneously using CaC2
Driving dimethyl carbonate synthesis from CO2 and methanol and production of acetylene simultaneously using CaC2
复制标题
利用 CaC2 驱动 CO2 和甲醇合成碳酸二甲酯并同时生产乙炔
DOI：
10.1039/c8cc01005f
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发表时间：
2018-04-28
影响因子：
4.9
通讯作者：
Han, Buxing
中科院分区：
文献类型：
--
作者：
Zhang, Zhaofu;Liu, Shuaishuai;Han, Buxing
由CO2和甲醇合成碳酸二甲酯（DMC）是一个非常有趣的反应，但受到工艺限制。在本工作中，CaC2消耗反应中产生的水以移动反应平衡，同时产生C2H2。这是第一个工作的结合驱动一个化学上不利的反应和生产C2H2使用CaC2。
The synthesis of dimethyl carbonate (DMC) from CO2 and methanol is a very interesting reaction, but is thermodynamically limited. In this work, CaC2 was used to consume the water produced in the reaction to shift the reaction equilibrium, and C2H2 was produced at the same time. This is the first work on the combination of driving a thermodynamically unfavorable reaction and producing C2H2 using CaC2.