THE DETERMINATION OF SURFACE TENSION WITH VERY SMALL VOLUMES OF LIQUID, AND THE SURFACE TENSIONS OF OCTANES AND XYLENES AT SEVERAL TEMPERATURES
THE DETERMINATION OF SURFACE TENSION WITH VERY SMALL VOLUMES OF LIQUID, AND THE SURFACE TENSIONS OF OCTANES AND XYLENES AT SEVERAL TEMPERATURES
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极小体积液体表面张力的测定，以及辛烷和二甲苯在几个温度下的表面张力
DOI：
10.1021/ja01670a012
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发表时间：
1924
影响因子：
15
通讯作者：
E. K. Carver
中科院分区：
文献类型：
--
作者：
T. W. Richards;C. L. Speyers;E. K. Carver
有时需要测定只有很小体积的液体的表面张力。这种测定可以在一个小的U形管中最方便地进行，U形管的一个臂是细毛细管，另一个臂是稍宽的管，内径不超过2毫米。1该方法需要特殊的预防措施，并具有特殊的优点，下面将进行讨论。1910年，已故的Clarence L.斯派尔斯在我们其中一人的指导下。由于对较宽管中液体高度的校正的精确大小存在疑问，因此迄今为止尚未公布结果。非常狭窄的管充分处理1这种方法可能是第一次使用弗兰肯海姆[福格。安，72，177（1847）]。后来，它也被Schiff [Ann.，223，47（1884）]，谁认为它的一些优势。这两个实验者都没有对结果进行令人满意的修正。Ostwald-Luther's“Physiko-Chemische Messungen，”1910，vol. 3，pp.第235-237章也不完整最近，YL· Shekhtman，Bull. acad. sci. russie [VI] 13，657-662（1919）;参见
Occasionally it is necessary to determine the surface tension of a liquid of which only a very small volume is available. This determination may be most conveniently carried out in a small U-tube of which one arm is a fine capillary, and the other a somewhat wider tube, not much over 2 mm. in internal diameter. 1 The method requiresspecial precautions, and has special advantages, which are discussed below. In 1910 the capillary constants ofoctanes and xylenes were thus meas-ured by the late Clarence L. Speyers under the direction of one of us. The results have not heretofore been published, because of question as to the precise magnitude of the correction to be applied to the height of liquid in the wider of the tubes. Very narrow tubes are adequately treated by1 This method was perhaps first used by Frankenheim [Fogg. Ann., 72, 177 (1847)]. Later it was also used by Schiff [Ann., 223, 47 (1884)], who perceived some of its advantages. Neither of these experimenters applied satisfactory corrections to the re-sults. The descriptionin Ostwald-Luther’s “Physiko-Chemische Messungen,” 1910, vol. 3, pp. 235-237 is also incomplete. Very recently a modification of the method has been used by YL· Shekhtman, Bull. acad. sci. russie [VI] 13, 657-662 (1919); see also