N-Bromosuccinimide-Mediated Conversion of Allyl Glycosides to Glycosyl Hemiacetals
N-Bromosuccinimide-Mediated Conversion of Allyl Glycosides to Glycosyl Hemiacetals
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DOI：
10.1080/07328301003664887
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发表时间：
2010-01-01
影响因子：
1
通讯作者：
Misra, Anup Kumar
中科院分区：
文献类型：
--
作者：
Panchadhayee, Rajib;Misra, Anup Kumar
在N-溴代丁二酰亚胺(NBS)存在下，开发了一种新的反应条件，用于将不同官能化的烯丙基糖苷水解成相应的糖基半缩醛衍生物。该反应条件特别快，温和，与低聚糖合成中使用的大多数官能团相容，产率很高。
A novel reaction condition has been developed for the hydrolysis of differentially functionalized allyl glycosides to their corresponding glycosyl hemiacetal derivatives in the presence of N-bromosuccinimide (NBS). The reaction condition is exceptionally fast, mild, and compatible with most of the functional groups used in the oligosaccharide synthesis, and yields were excellent.