A dinuclear triple-stranded helicate with a bis(benzene-o-dithiolato) ligand.
A dinuclear triple-stranded helicate with a bis(benzene-o-dithiolato) ligand.
复制标题
具有双（苯邻二硫醇）配体的双核三链螺旋。
作者：
F. E. Hahn;Thorsten Kreickmann;T. Pape
双（邻苯二硫醇）配体H4-1与Ti ~（4+）发生自组装反应，生成双核三链螺旋配合物[Ti ~（2（1）3）]4-，这是第一个完全由邻苯二硫醇配体构建的螺旋配合物。
The bis(benzene-o-dithiol) ligand H4-1 reacts with Ti4+ in a self-assembly reaction to give the dinuclear triple-stranded helicate [Ti2(1)3]4- which is the first helicate build exclusively from benzene-o-dithiolato donor groups.