Synthesis, Characterization, and Properties of Binuclear Gold(I) Phosphine Alkynyl Complexes
Synthesis, Characterization, and Properties of Binuclear Gold(I) Phosphine Alkynyl Complexes
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双核金(I)膦炔基配合物的合成、表征及性能
DOI：
10.1021/om1000919
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发表时间：
2010-05
期刊：
影响因子：
2.8
通讯作者：
Liu, Sheng Hua
中科院分区：
文献类型：
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作者：
Lin, Yan;Yin, Jun;Yuan, Jingjing;Hu, Ming;Li, Ziyong;Yu, Guang-Ao;Liu, Sheng Hua
金盐与各种π-共轭二炔的反应产生了两个同源系列的双核炔基金（I）配合物，线性刚性棒Cy 3 PAu −C C−（CH CH）n−C C− AuPCy 3（n = 1−3，all-transs）（2a-c）和光致变色LAu−C C−DTE−C C−AuL（DTE = 1，
Reactions of gold salts with various π-conjugated dialkynes have led to two homologous series of binuclear alkynylgold(I) complexes, linear rigid-rod Cy3PAu−C≡C−(CH═CH)n−C≡C−AuPCy3 (n = 1−3, all-trans) (2a−c) and photochromic LAu−C≡C−DTE−C≡C−AuL (DTE = 1,