Recent advances in the synthesis and applications of 2,6-dipyrazolylpyridine derivatives and their complexes
Recent advances in the synthesis and applications of 2,6-dipyrazolylpyridine derivatives and their complexes
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DOI：
10.1039/c3nj00835e
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发表时间：
2014-01-01
影响因子：
3.3
通讯作者：
Halcrow, Malcolm A.
中科院分区：
文献类型：
--
作者：
Halcrow, Malcolm A.
综述了近8年来2，6-二(吡唑-1-基)吡啶(1-BPP)和2，6-二(吡唑-3-基)吡啶(3-BPP)及其衍生物及其配合物的化学研究进展。特别的进展包括：多功能自旋交叉开关的合成；在生物医学传感器中引入发射f元件吊舱和中心；各种功能软材料和表面结构的自组装；以及3-BPP络合物在催化中的应用。
Developments in the chemistry of 2,6-di(pyrazol-1-yl) pyridine (1-bpp) and 2,6-di(pyrazol-3-yl)pyridine (3-bpp), their derivatives and their complexes are surveyed, with emphasis on the last eight years. Particular advances include the synthesis of multi-functional spin-crossover switches; the incorporation of emissive f-element podand centres into biomedical sensors; the self-assembly of a variety of functional soft materials and surface structures; and, the use of 3-bpp complexes in catalysis.